You may be able to do this, but you need to be familiar with how regular expressions work.
If I have a collection that contains the items Apple, Orange, and Cherry, I can use the form function Converttostring to have it return this: Apple,Orange,Cherry
I can then use the replace form function, to replace everything in that string except for the nth section. This would use a regular expression, and how that expression is written depends on the contents of your collection. The example below is the simplest example, and it assumes your collection is only made of strings and that no commas are in the collection (So that the only commas present are separating the items).
Collection Variable (TestC) items:
Apple
Orange
Cherry
Main Form Setup:
CollectionString Variable:
convertToString(tWorkflow].WUser defined variables].aTestC])